Some info. that probably will be very helpful...
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To unsubscribe or not to unsubscribe?
If you have signed up for a newsletter or product updates, or otherwise agreed to receive email from a legitimate company, you owe it to the sender to at least try the removal process provided in the email before you cry "spam!" It is very difficult for a legitimate sender to remove you from their list if they learn about the problem from SpamCop. So it's generally much more effective to remove yourself using the sender's procedure. If you have tried unsubscribing to no avail, but you think the company normally makes an honest attempt to remove people, then you can file a spam report, but please include a note stating what you have done to try to be removed in the comments section of your spam report - you will have an option to add comments to all your spam reports. This will lend credence to your claim of spamming
The dangers of unsubscribing
However, if the email is not from a legitimate organization that you have had prior communication with, then following the removal instructions in the spam usually just gets you more spam. By using the removal instructions, you have verified that you received the spam and read it. That makes your email address even more valuable to the spammer, and you will just get even more junk in the future. Normally, we recommend that you never reply to spam email, or trust any of the information in the spam unless you really know what information you can and cannot trust. For instance, if you get a spam from john@aol.com, you should not reply to john@aol.com, nor should you report the spam to aol's abuse administrator (abuse@aol.com). Usually, most of the information in the header of the spam is "forged." Just as you can put any return address on a normal paper letter, spammers can put any return address they want on their email. Usually, the return address belongs to someone the spammer wants to annoy with a bunch of erroneous complaints.